On 13 October 2007 he beat Ecuador in Quito with a free kick, a 1-0 result that ended six years without a home defeat for the hosts, and on 6 September 2008 he became the first Venezuelan to play 100 internationals. Rey played in six Copa América tournaments, including the fourth place of 2011 that stands as Venezuela's best, won five Venezuelan league titles with Caracas and the Chilean championship with Colo-Colo in 2009. Career record: 115 caps and 11 goals for Venezuela; club career at Caracas Fútbol Club, Club Sport Emelec, Asociación Civil Deportivo Lara.
| 1993–1994 | C.S. Marítimo de La Guaira |
| 1995–1996 | Deportivo Fabril |
| 1996–2002 | Caracas Fútbol Club |
| 1999–1999 | Club Sport Emelec |
| 2000–2000 | Dundee |
| 2003–2003 | Club Sport Emelec |
| 2004–2005 | Pontevedra CF |
| 2006–2006 | Atlético Nacional |
| 2006–2010 | Caracas Fútbol Club |
| 2007–2008 | AEK Larnaca |
| 2009–2009 | Club Social y Deportivo Colo Colo |
| 2011–2015 | Asociación Civil Deportivo Lara |
| Venezuela | 115 caps, 11 goals |
Venezuela legends whose careers overlapped Rey's
One rank above: Darwin Machís at #7.
One rank below: Roberto Rosales at #9.
Venezuela's editorial top five: Juan Arango · Salomón Rondón · Tomás Rincón · Josef Martínez · Rafael Dudamel.