
A week after his debut he scored in Syria's 9-0 win over Laos on 11 May 2001, and eighteen years later, on 5 September 2019 against the Philippines, he became the first Asian to play in six World Cup qualifying campaigns. He remains Syria's record scorer with 36 goals in 72 caps, and in Kuwait he won four league titles, six Emir Cups and four golden boots, the last with 23 goals in 2015-16. Career record: 51 caps and 26 goals for Syria; club career at Al-Karamah SC, Al-Arabi SC, Shanghai Shenhua.
| 2000–2002 | Al-Karamah SC |
| 2002–2003 | Al Nasr Sporting Club |
| 2003–2009 | Al-Arabi SC |
| 2005–2005 | Al Ahli SC |
| 2009–2011 | Qadsia SC |
| 2011–2012 | Umm Salal SC |
| 2012–2013 | Zakho S.C. |
| 2012–2012 | Qadsia SC |
| 2013–2014 | Shanghai Shenhua |
| 2014–today | Al-Arabi SC |
| Syria | 51 caps, 26 goals |
Syria legends whose careers overlapped Al-Khatib's
One rank above: Omar Khribin at #2.
One rank below: Jehad Al-Hussain at #4.
Syria's editorial top five: Omar Al-Somah · Omar Khribin · Firas Al-Khatib · Jehad Al-Hussain · Raja Rafe.