On 20 February 2007 he played for PSV against Arsenal and became the first Chinese footballer to appear in the Champions League, three days after becoming the first to play in the Eredivisie. Home again, he won four Chinese Super League titles in a row with Guangzhou Evergrande from 2011 and the 2013 AFC Champions League, and he finished runner-up with China at the 2004 Asian Cup in a career of 69 caps. Career record: 69 caps and 5 goals for China; club career at Shanghai Shenhua, FK Austria Wien, Guangzhou.
| 2002–2010 | Shanghai Shenhua |
| 2007–2007 | PSV Eindhoven |
| 2008–2009 | FK Austria Wien |
| 2010–2014 | Guangzhou |
| 2015–today | Shanghai Port |
| China | 69 caps, 5 goals |
China legends whose careers overlapped Xiang's
One rank above: Su Maozhen at #24.
One rank below: Wu Xi at #26.
China's editorial top five: Sun Jihai · Zheng Zhi · Fan Zhiyi · Hao Haidong · Gu Guangming.